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51.
We have investigated the H and Cl systematics in apatite from four brecciated lunar meteorites. In Northwest Africa (NWA) 4472, most of the apatites contain ~2000–6000 ppm H2O with δD between ?200 and 0‰, except for one grain isolated in the matrix, which contains ~6000 ppm H2O with δD of ~500–900‰. This low‐δD apatite contains ~2500–7500 ppm Cl associated with δ37Cl of ~15–20‰, while the high‐δD grain contains ~2500 ppm Cl with δ37Cl of ~7–15‰. In NWA 773, apatites in a first group contain ~700–2500 ppm H2O with δD values averaging around ~0 ± 100‰, while apatites in a second group contain ~5500–16500 ppm H2O with δD ~250 ± 50‰. In Sayh al Uhaymir (SaU) 169 and Kalahari (Kal) 009, apatites are similar in terms of their H2O contents (~600–3000 ppm) and δD values (?100 to 200‰). In SaU 169, apatites contain ~6000–10,000 ppm Cl, characterized by δ37Cl of ~5–12‰. Overall, most of the analyzed apatite grains have δD within the range reported for carbonaceous chondrites, similar to apatite analyzed in ancient (>3.9 Ga) lunar magmatic. One grain in NWA 4472 has H and Cl isotope compositions similar to apatite from mare basalts. With an age of 4.35 Ga, this grain could be a representative of the oldest known lunar volcanic activity. Finally, since numerous evolved clasts in NWA 773 formed through silicate liquid immiscibility, the apatite grains with extremely high H2O contents, reaching pure hydroxylapatite composition, could provide insights into the effects of such process on the evolution of volatiles in lunar magmas.  相似文献   
52.
Small bodies of the solar system are now the targets of space exploration. Many of these bodies have elongated, non-spherical shapes, and the usual spherical harmonic expansions of their gravity fields are not well suited for the modelling of spacecraft orbits around these bodies. An elegant remedy is to use ellipsoidal harmonic expansions instead of the usual spherical ones. In this paper, we present their mathematical theory as well as a real application: the simulation of a landing on the surface of a kilometer-sized comet. We show that with an ellipsoidal harmonic expansion up to degree 5, the error on the landing position is at the meter level, while the corresponding error for the spherical harmonic expansion can reach tens of meters.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献   
53.
Afroosa  M.  Rohith  B.  Paul  Arya  Durand  Fabien  Bourdallé-Badie  Romain  Joseph  Sudheer  Prerna  S.  Shenoi  S. S. C. 《Ocean Dynamics》2022,72(7):523-538
Ocean Dynamics - An intraseasonal see-saw has been observed in the Indo-Pacific barotropic sea level anomaly during boreal winters. This see-saw carries a significant amount of energy and is...  相似文献   
54.
Recent studies geared toward understanding the volatile abundances of the lunar interior have focused on the volatile‐bearing accessory mineral apatite. Translating measurements of volatile abundances in lunar apatite into the volatile inventory of the silicate melts from which they crystallized, and ultimately of the mantle source regions of lunar magmas, however, has proved more difficult than initially thought. In this contribution, we report a detailed characterization of mesostasis regions in four Apollo mare basalts (10044, 12064, 15058, and 70035) in order to ascertain the compositions of the melts from which apatite crystallized. The texture, modal mineralogy, and reconstructed bulk composition of these mesostasis regions vary greatly within and between samples. There is no clear relationship between bulk‐rock basaltic composition and that of bulk‐mesostasis regions, indicating that bulk‐rock composition may have little influence on mesostasis compositions. The development of individual melt pockets, combined with the occurrence of silicate liquid immiscibility, exerts greater control on the composition and texture of mesostasis regions. In general, the reconstructed late‐stage lunar melts have roughly andesitic to dacitic compositions with low alkali contents, displaying much higher SiO2 abundances than the bulk compositions of their host magmatic rocks. Relevant partition coefficients for apatite‐melt volatile partitioning under lunar conditions should, therefore, be derived from experiments conducted using intermediate compositions instead of compositions representing mare basalts.  相似文献   
55.
The spatial distribution of soil shear-wave velocity and the fundamental period of vibration were selected as input parameters for the determination of potential seismic site effects in the Saguenay region, Canada. The methodology used in this study involved three clear steps. First, a 3D geological model of the surficial deposits was built taking into consideration the type, spatial distribution and thickness of the deposits. Second, representative average Vs values were determined for each of the major soil units. Finally, the average shear-wave velocity from the ground surface to bedrock (Vsav), the shear-wave velocity of the upper 30 m (Vs30) and the fundamental site resonance period (T0) were calculated over a regular grid for the study area. The results include the spatial distribution of the fundamental site resonance period, the average shear-wave velocity in the first 30 m of the ground and the spatial distribution of National Building Code of Canada seismic soil classes for the Saguenay region.  相似文献   
56.
Understanding groundwater/surface-water interactions in wetlands is crucial because wetlands provide not only a high potential for agricultural production, but also sensitive and valuable ecosystems. This is especially true for the Kilombero floodplain wetland in Tanzania, which represents a data-scarce region in terms of hydrological and hydrogeological data. A comprehensive approach combining hydrogeological with tracer-based assessments was conducted, in order to develop a conceptual hydrogeological wetland model of the area around the city of Ifakara in the north-eastern region of Kilombero catchment. Within the study site, a heterogeneous porous aquifer, with a range of hydraulic conductivities, is underlain by a fractured-rock aquifer. Groundwater chemistry is mainly influenced by silicate weathering and depends on groundwater residence times related to the hydraulic conductivities of the porous aquifer. Groundwater flows from the hillside to the river during most of the year. While floodwater close to the river is mainly derived from overbank flow of the river, floodwater at a greater distance from the river mainly originates from precipitation and groundwater discharge. Evaporation effects in floodwater increase with increasing distance from the river. In general, the contribution of flood and stream water to groundwater recharge is negligible. In terms of an intensification of agricultural activities in the wetland, several conclusions can be drawn from the conceptual model. Results of this study are valuable as a base for further research related to groundwater/surface-water interactions and the conceptual model can be used in the future to set up numerical flow and transport models.  相似文献   
57.
Distinction between active and legacy sources of nutrients is needed for effective reduction of waterborne nutrient loads and associated eutrophication. This study quantifies main typological differences in nutrient load behaviour versus water discharge for active and legacy sources. This quantitative typology is used for source attribution based on monitoring data for water discharge and concentrations of total nitrogen (TN) and total phosphorous (TP) from 37 catchments draining into the Baltic Sea along the coastline of Sweden over the period 2003–2013. Results indicate dominant legacy source contributions to the monitored loads of TN and TP in most (33 of the total 37) study catchments. Dominant active sources are indicated in 1 catchment for TN, and mixed sources are indicated in 3 catchments for TN, and 4 catchments for TP. The TN and TP concentration contributions are quantified to be overall higher from the legacy than the active sources. Legacy concentrations also correlate well with key indicators of human activity in the catchments, agricultural land share for TN (R2 = 0.65) and population density for TP (R2 = 0.56). Legacy-dominated nutrient concentrations also change more slowly than in catchments with dominant active or mixed sources. Various data-based results and indications converge in indicating legacy source contributions as largely dominant, mainly anthropogenic, and with near-zero average change trends in the present study of catchments draining into the Baltic Sea along the coastline of Sweden, as in other parts of the world. These convergent indications emphasize needs to identify and map the different types of sources in each catchment, and differentiate strategies and measures to target each source type for possible achievement of shorter- and longer-term goals of water quality improvement.  相似文献   
58.
A von Neumann stability analysis of the discretized conservation equation for single-phase porous media flows is performed, where non-Newtonian and non-Darcy effects are accounted for using a velocity (or mass flux)-dependent mobility factor. Comprehensive results in three dimensions for two low-order finite-volume discretizations typically encountered in reservoir simulation are provided, based on edge-centered and upstream cell-centered mobility calculations. It is found that common semi-implicit schemes, where the pressure gradient driving the flow is taken implicitly while the velocity-dependent mobility is evaluated explicitly, are subject to restrictions on the logarithmic derivative of mobility with respect to velocity. A remarkable new result is nevertheless obtained: for any physically acceptable strength of non-Newtonian and non-Darcy effects, there exists a stable and explicit method to evaluate the mobility, rendering the need to implement costly fully implicit schemes more difficult to justify.  相似文献   
59.
We provide new insights into the prograde evolution of HP/LT metasedimentary rocks on the basis of detailed petrologic examination, element-partitioning analysis, and thermodynamic modelling of well-preserved Fe–Mg–carpholite- and Fe–Mg–chloritoid-bearing rocks from the Afyon Zone (Anatolia). We document continuous and discontinuous compositional (ferromagnesian substitution) zoning of carpholite (overall X Mg = 0.27–0.73) and chloritoid (overall X Mg = 0.07–0.30), as well as clear equilibrium and disequilibrium (i.e., reaction-related) textures involving carpholite and chloritoid, which consistently account for the consistent enrichment in Mg of both minerals through time, and the progressive replacement of carpholite by chloritoid. Mg/Fe distribution coefficients calculated between carpholite and chloritoid vary widely within samples (2.2–20.0). Among this range, only values of 7–11 correlate with equilibrium textures, in agreement with data from the literature. Equilibrium phase diagrams for metapelitic compositions are calculated using a newly modified thermodynamic dataset, including most recent data for carpholite, chloritoid, chlorite, and white mica, as well as further refinements for Fe–carpholite, and both chloritoid end-members, as required to reproduce accurately petrologic observations (phase relations, experimental constraints, Mg/Fe partitioning). Modelling reveals that Mg/Fe partitioning between carpholite and chloritoid is greatly sensitive to temperature and calls for a future evaluation of possible use as a thermometer. In addition, calculations show significant effective bulk composition changes during prograde metamorphism due to the fractionation of chloritoid formed at the expense of carpholite. We retrieve PT conditions for several carpholite and chloritoid growth stages (1) during prograde stages using unfractionated, bulk-rock XRF analyses, and (2) at peak conditions using compositions fractionated for chloritoid. The PT paths reconstructed for the Kütahya and Afyon areas shed light on contrasting temperature conditions for these areas during prograde and peak stages.  相似文献   
60.
Chemical and isotopic data for 23 geothermal water samples collected in New Zealand within the Taupo Volcanic Zone (TVZ) are reported. Major and trace elements including Li, B and Sr and their isotopic compositions (δ7Li, δ11B, 87Sr/86Sr) were determined in high temperature geothermal waters collected from deep boreholes in different geothermal fields (Ohaaki, Wairakei, Mokai, Kawerau and Rotokawa geothermal systems). Lithium concentrations are high (from 4.5 to 19.9 mg/L) and Li isotopic compositions (δ7Li) are homogeneous, ranging between −0.5‰ and +1.4‰. In particular, it is noteworthy that, except for the samples from the Kawerau geothermal field having slightly higher δ7Li values (+1.4%), the other geothermal waters have a near constant δ7Li signature around a mean value of 0‰ ± 0.6 (2σ, n = 21). Boron concentrations are also high and relatively homogeneous for the geothermal samples, falling between 17.5 and 82.1 mg/L. Boron isotopic compositions (δ11B) are all negative, and display a range between −6.7‰ and −1.9‰. These B isotope compositions are in agreement with those of the Ngawha geothermal field in New Zealand. Lithium and B isotope signatures are in a good agreement with a fluid signature mainly derived from water/rock interaction involving magmatic rocks with no evidence of seawater input. On the other hand, Sr concentrations are lower and more heterogeneous and fall between 2 and 165 μg/L. The 87Sr/86Sr ratios range from 0.70549 to 0.70961. These Sr isotope compositions overlap those of the Rotorua geothermal field in New Zealand, confirming that some geothermal waters (with more radiogenic Sr) have interacted with bedrocks from the metasedimentary basement. Each of these isotope systems on their own reveals important information about particular aspects of either water source or water/rock interaction processes, but, considered together, provide a more integrated understanding of the geothermal systems from the TVZ in New Zealand.  相似文献   
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